Synthesis and chemistry of novel dendritic macromolecules possessing internal electroactive anthraquinonoid moieties

被引：29

作者：

Newkome, GR

Narayanan, VV

Echegoyen, L

PerezCordero, E

Luftmann, H

机构：

[1] UNIV MIAMI, DEPT CHEM, CORAL GABLES, FL 33124 USA

[2] UNIV MUNSTER, D-4400 MUNSTER, GERMANY

来源：

MACROMOLECULES | 1997年 / 30卷 / 17期

关键词：

D O I：

10.1021/ma9703214

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel series of structured dendritic macromolecules incorporating covalently linked diaminoanthraquinones was synthesized. C nuclear magnetic resonance (NMR) studies confirmed the formation of an amino triester from the reaction of 1,4-diaminoanthraquinone (1,4-DAAQ) with glutaryl chloride and an amine. 1H NMR spectra together with elemental analysis and MALDI-TOF mass spectra of the compounds support a hydrogen-bonded, cyclic conformation. Voltammetric studies reveal the electrochemical behavior and redox properties of the dendritic macromolecules.

引用

页码：5187 / 5191

页数：5

共 37 条

[1]

[Anonymous], ADV DENDR MACROMOL

[2]

ARDOIN N, 1995, B SOC CHIM FR, V132, P875

[3]

BODANSZKY M, 1984, REACTIVITY STRUCTURE, V21, P145

[4]

CHEN Z, 1992, J AM CHEM SOC, V114, P441