On Pd carbide formation and vinyl acetate synthesis

被引：23

作者：

Bowker, M ^{[1
]}

Morgan, C ^{[1
]}

机构：

[1] Univ Wales Coll Cardiff, Sch Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

CATALYSIS LETTERS | 2004年 / 98卷 / 01期

关键词：

Acetate; Physical Chemistry; Carbide; Catalysis; Vinyl;

D O I：

10.1007/s10562-004-6448-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The formation of Pd carbide during the synthesis of vinyl acetate was investigated. The formation of carbide had resulted in the deactivation of Pd catalysts. The adsorption, desorption, and reaction of a number of organics on Pd (110), including ethene, acetic acid, vinyl acetate, and acetaldehyde were investigated. It was found that above 450 K the ethene continuously adsorbed on the Pd surfaces with high probability, even though the molecule decomposed to release hydrogen into the gas phase and deposited carbon atoms on the surfaces.

引用

页码：67 / 67

页数：1

共 4 条

[1] Acetic acid adsorption and decomposition on Pd(110) [J].

Bowker, M ;

Morgan, C ;

Couves, J .

SURFACE SCIENCE, 2004, 555 (1-3) :145-156

[2] The molecular beam reactor [J].

Bowker, M .

APPLIED CATALYSIS A-GENERAL, 1997, 160 (01) :89-98

[3] The formation of PdCx over Pd-based catalysts in vapor-phase vinyl acetate synthesis:: does a Pd-Au alloy catalyst resist carbide formation? [J].

Han, YF ;

Kumar, D ;

Sivadinarayana, C ;

Clearfield, A ;

Goodman, DW .

CATALYSIS LETTERS, 2004, 94 (3-4) :131-134

[4]

MORGAN C, IN PRESS

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