Redox inversion of helicity in propeller-shaped molecules derived from S-methyl cysteine and methioninol

被引：39

作者：

Barcena, HS ^{[1
]}

Holmes, AE ^{[1
]}

Zahn, S ^{[1
]}

Canary, JW ^{[1
]}

机构：

[1] NYU, Dept Chem, New York, NY 10003 USA

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 05期

关键词：

D O I：

10.1021/ol0275217

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] One-electron reduction inverts the helicity of copper complexes formed from derivatives of S-methylcysteine and methioninol. The change in conformation of the organic ligand is followed in the exciton-coupled circular dichroism (ECCD) spectra of the complexes.

引用

页码：709 / 711

页数：3

共 27 条

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[2]

2-G

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