Synthesis and characterization of tricyanovinyl-capped oligothiophenes as low-band-gap organic materials

被引：65

作者：

Pappenfus, TM ^{[1
]}

Burand, MW ^{[1
]}

Janzen, DE ^{[1
]}

Mann, KR ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 09期

关键词：

D O I：

10.1021/ol034317q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Tricyanovinyl-capped oligothlophenes of up to six rings have been synthesized and characterized. The substituted oligomers display dramatic reductions in both their optical and electrochemical band gaps in comparison to unsubstituted oligomers. The solvatochromic behavior of the terthiophene-substituted molecule was investigated in a variety of solvents. Stable oxidations and reductions were exhibited by the sexithiophene-substituted molecule on the CV time scale.

引用

页码：1535 / 1538

页数：4

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