On the symmetry of the morphotropic phase boundary in ferroelectric BiScO3-PbTiO3 system

被引：28

作者：

Datta, K. ^{[1
]}

Gorfman, S. ^{[1
]}

Thomas, P. A. ^{[1
]}

机构：

[1] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England

来源：

APPLIED PHYSICS LETTERS | 2009年 / 95卷 / 25期

基金：

英国工程与自然科学研究理事会;

关键词：

Bismuth compounds - Lead titanate - Titanium compounds;

D O I：

10.1063/1.3268478

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

A single crystal of (1-x) BiScO3-xPbTiO(3) at x=0.64, which is the morphotropic phase boundary composition for this system, has been investigated utilizing two different types of diffractometry. A total of twenty different reciprocal space maps for different Bragg reflections {hkl} were collected to study their individual splittings. It has been shown that to explain the 2 theta splittings observed, a two-phase model is necessary. The best model found consists of either two primitive orthorhombic or two primitive monoclinic lattices and the models previously proposed based on powder diffraction data, consisting rhombohedral or tetragonal symmetries, can be rejected. (C) 2009 American Institute of Physics. [doi:10.1063/1.3268478]

引用

页数：3

共 14 条

[1] Origin of morphotropic phase boundaries in ferroelectrics [J].

Ahart, Muhtar ;

Somayazulu, Maddury ;

Cohen, R. E. ;

Ganesh, P. ;

Dera, Przemyslaw ;

Mao, Ho-Kwang ;

Hemley, Russell J. ;

Ren, Yang ;

Liermann, Peter ;

Wu, Zhigang .

NATURE, 2008, 451 (7178) :545-U2

[2] Morphotropic phase boundaries in (BiScO3)1-x(PbTiO3)x (0.60<x<0.75) and their relation to chemical composition and polar order [J].

Chaigneau, J. ;

Kiat, J. M. ;

Malibert, C. ;

Bogicevic, C. .

PHYSICAL REVIEW B, 2007, 76 (09)

[3] Phase diagram of the perovskite system (1-x)BiScO3-xPbTiO3 [J].

Eitel, RE ;

Zhang, SJ ;

Shrout, TR ;

Randall, CA ;

Levin, I .

JOURNAL OF APPLIED PHYSICS, 2004, 96 (05) :2828-2831

[4] Preparation and characterization of high temperature perovskite ferroelectrics in the solid-solution (1-x)BiScO3-xPbTiO3 [J].

Eitel, RE ;

Randall, CA ;

Shrout, TR ;

Park, SE .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2002, 41 (4A) :2099-2104

[5] New high temperature morphotropic phase boundary piezoelectrics based on Bi(Me)O3-PbTiO3 ceramics [J].

Eitel, RE ;

Randall, CA ;

Shrout, TR ;

Rehrig, PW ;

Hackenberger, W ;

Park, SE .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2001, 40 (10) :5999-6002

[6] High-pressure synthesis and ferroelectric properties in perovskite-type BiScO3-PbTiO3 solid solution [J].

Inaguma, Y ;

Miyaguchi, A ;

Yoshida, M ;

Katsumata, T ;

Shimojo, Y ;

Wang, RP ;

Sekiya, T .

JOURNAL OF APPLIED PHYSICS, 2004, 95 (01) :231-235

[7] Temperature-dependent neutron diffraction study of phase separation at morphotropic phase boundary in (1-x)BiScO3-xPbTiO3 [J].

Kim, Bongju ;

Tong, P. ;

Kwon, Daeyoung ;

Park, J. M. S. ;

Kim, Bog G. .

JOURNAL OF APPLIED PHYSICS, 2009, 105 (11)

[8] A monoclinic ferroelectric phase in the Pb(Zr1-xTix)O3 solid solution [J].

Noheda, B ;

Cox, DE ;

Shirane, G ;

Gonzalo, JA ;

Cross, LE ;

Park, SE .

APPLIED PHYSICS LETTERS, 1999, 74 (14) :2059-2061

[9] Polarization rotation via a monoclinic phase in the piezoelectric 92% PbZn1/3Nb2/3O3-8% PbTiO3 [J].

Noheda, B ;

Cox, DE ;

Shirane, G ;

Park, SE ;

Cross, LE ;

Zhong, Z .

PHYSICAL REVIEW LETTERS, 2001, 86 (17) :3891-3894

[10] Transmission electron microscopy investigation of the high temperature BiScO3-PbTiO3 piezoelectric ceramic system [J].

Randall, CA ;

Eitel, RE ;

Shrout, TR ;

Woodward, DI ;

Reaney, IM .

JOURNAL OF APPLIED PHYSICS, 2003, 93 (11) :9271-9274

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