Synthesis, characterization and structure of metallocene dicyanamide complexes

被引：14

作者：

Honzicek, J

Erben, M

Císarová, I

Vinklárek, J

机构：

[1] Univ Pardubice, Dept Gen & Inorgan Chem, Pardubice 53210, Czech Republic

[2] Charles Univ, Dept Inorgan Chem, Prague 12840 2, Czech Republic

来源：

INORGANICA CHIMICA ACTA | 2005年 / 358卷 / 03期

关键词：

titanocene; vanadocene; pseudohalide; dicyanamide complexes; X-ray structure; NMR spectroscopy; EPR spectroscopy; mass spectrometry;

D O I：

10.1016/j.ica.2004.09.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bis(cyclopentadienyl) complexes [Cp2Ti(dca)](2)O and Cp2V(dca)(2) (dca = dicyanamide) have been prepared by reaction of sodium dicyanamide with aqueous solution of titanocene dichloride and vanadocene dichloride, respectively. The X-ray structure analyses of both complexes confirmed monodentate coordination of dicyanamide ligand through the terminal nitrogen atom of cyano group. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：814 / 819

页数：6

共 29 条

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