Photosensitization via dye coordination: A new strategy to synthesize metal nitrosyls that release NO under visible light

被引：70

作者：

Rose, Michael J.

Olmstead, Marilyn M.

Mascharak, Pradip K. ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 17期

关键词：

D O I：

10.1021/ja070247x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct coordination of the dye resorufin (Resf) to the ruthenium center photosensitizes the Ru-NO bond and improves NO photolability of the designed {Ru-NO}(6) nitrosyl [(Me(2)bpb)Ru(NO)(Resf)] under visible light.

引用

页码：5342 / +

页数：3

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