New bisamides gelators:: relationship between chemical structure and fiber morphology

被引：28

作者：

Schmidt, R ^{[1
]}

Adam, FB ^{[1
]}

Michel, M ^{[1
]}

Schmutz, M ^{[1
]}

Decher, G ^{[1
]}

Mésini, PJ ^{[1
]}

机构：

[1] Inst Charles Sadron, F-67083 Strasbourg, France

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 15期

关键词：

gels; organogelators; bisamides; electron microscopy;

D O I：

10.1016/S0040-4039(03)00456-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Different dialkoxybenzoic acid derivatives with identical alkyl chain lengths were synthesized and their properties as organogelators evaluated. Only the compounds bearing amide groups behave like gelators. Their gelation abilities and phase diagrams were described. A structural study was conducted by freeze-fracture electron microscopy and showed that the methyl ester formed platelet-like aggregates whereas the corresponding free acid formed thin fibers in the gel. (C) 2003 Elsevier Science Ltd. All rights reserved.

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页码：3171 / 3174

页数：4

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