Quantitative analyses of the seven isomeric 3,4- and 3,6-dimethylcyclohexenes by gas chromatography

被引:10
作者
Baldwin, JE [1 ]
Burrell, RC [1 ]
机构
[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA
关键词
D O I
10.1021/jo000956s
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Quantitative analyses of mixtures of the seven isomeric 3,4- and 3,6-dimethylcyclohexenes have been achieved by gas chromatography. Correlations of structure and absolute stereochemistry with elution order have been made rigorously with the aid of authentic. optically active samples all derived from (3R)-methylcyclohexanone.
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页码:7145 / 7150
页数:6
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