Facile formation of N-confused porphyrin dimers by platinum(II) coordination to the outer-nitrogen atoms

被引：58

作者：

Furuta, H

Youfu, K

Maeda, H

Osuka, A

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan

[2] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 19期

关键词：

macrocycles; macrocyclic ligands; N ligands; platinum; porphyrinoids;

D O I：

10.1002/anie.200350995

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Confusion but no doubt: Two types of PtII dimer complexes of N-confused porphyrin (depicted) were synthesized and the structures were unequivocally elucidated by X-ray crystal analyses. Both complexes contain a metallocycle that binds to a Pt center by an outer-nitrogen atom of the confused porphyrin, and by an orthocarbon atom of a meso-aryl group.

引用

页码：2186 / 2188

页数：3

共 25 条

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