Polymer-supported organic reactions: what takes place in the beads?

被引：226

作者：

Hodge, P ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL SOCIETY REVIEWS | 1997年 / 26卷 / 06期

关键词：

D O I：

10.1039/cs9972600417

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of polymer-supported reactants in organic synthesis is currently of considerable interest, especially in the context of combinatorial syntheses. To carry out successfully reactions using polymer-supported reactants it is important to be aware of what takes place inside the beads. Examples are presented in this article which show that compared to the analogous homogeneous reaction systems, polymer-supported reactions can show substrate selectivity, be slower or faster, follow a different reaction course, or give a significantly different stereochemical result.

引用

页码：417 / 424

页数：8

共 36 条

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