Ostwald ripening, chiral crystallization, and the common-ancestor effect

被引:77
作者
Cartwright, Julyan H. E. [1 ]
Piro, Oreste
Tuval, Idan
机构
[1] CSIC, Lab Estudios Cristalog, E-18100 Armilla, Granada, Spain
[2] Univ Illes Balears, CSIC, Inst Mediterrani Estudis Avancats, E-07071 Palma de Mallorca, Spain
[3] Univ Cambridge, DAMTP, Ctr Math Sci, Cambridge CB3 0WA, England
关键词
D O I
10.1103/PhysRevLett.98.165501
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We introduce an agent-based model for advection-mediated chiral autocatalysis in which we take into account dissolution-crystallization processes through Ostwald ripening. We demonstrate that the latter phenomenon is the key to explaining previously puzzling experimental results whereby complete chiral symmetry breaking is attained from an initially unbiased mixture of seed crystals. We show that this homochirality is achieved by what has been termed the common-ancestor effect: Ostwald ripening removes competing lineages, leaving only one common ancestor for the entire system.
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页数:4
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