Reactivity of [Cp2Ti(CO)2] and B(C6F5)3:: Formation of the acylborane complexes [Cp2Ti(CO)(η2-OCB(C6F5)3)] and [Cp2Ti(THF)(η2-OCB(C6F5)3)]

被引：22

作者：

Choukroun, R ^{[1
]}

Lorber, C ^{[1
]}

Lepetit, C ^{[1
]}

Donnadieu, B ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 10期

关键词：

D O I：

10.1021/om030185t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction Of [Cp2Ti(CO)(2)] with B(C6F5)(3) leads, surprisingly, as revealed by X-ray structure determination to the unexpected titana acylborane [CP2Ti(L)(eta(2)-OCB(C6F5)(3))] (1, L = CO, "O-outside" configuration; 2, L = THF, "O-inside" configuration) with the tris(perfluorophenyl)borane, as a Lewis acid, attached to the carbonyl carbon atom. The acylborane picture is strengthened by a theoretical calculation (ELF).

引用

收藏

页码：1995 / 1997

页数：3

相关论文

共 40 条

[1] Synthesis and characterization of new alkyl-carbon dioxide compounds and the first neutral acyl-carbonyl niobocene complexes [J].

Antinolo, A ;

CarrilloHermosilla, F ;

delHierro, I ;

Otero, A ;

Fajardo, M ;

Mugnier, Y .

ORGANOMETALLICS, 1997, 16 (19) :4161-4166

[2] CRYSTAL AND MOLECULAR-STRUCTURE OF TITANOCENE DICARBONYL, (H5-C5H5)2TI(CO)2 [J].

ATWOOD, JL ;

STONE, KE ;

ALT, HG ;

HRNCIR, DC ;

RAUSCH, MD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 96 (01) :C4-C6

[3] Solution and solid-state characteristics of imine adducts with tris(pentafluorophenyl)borane [J].

Blackwell, JM ;

Piers, WE ;

Parvez, M ;

McDonald, R .

ORGANOMETALLICS, 2002, 21 (07) :1400-1407

[4] SYNTHESIS OF CATIONIC ALKYL BIS(CYCLOPENTADIENYL)TITANIUM COMPLEXES BY ONE-ELECTRON OXIDATION OF TITANIUM(III) ALKYLS - THE STRUCTURE OF [CP2STARTIME(THF)]BPH4 AND [CP2STARTI(OH)(H2O)]BPH4.2THF [J].

BOCHMANN, M ;

JAGGAR, AJ ;

WILSON, LM ;

HURSTHOUSE, MB ;

MOTEVALLI, M .

POLYHEDRON, 1989, 8 (13-14) :1838-1843

[5] SYNTHESIS AND STRUCTURE OF NOVEL GROUP-IV TRIDENTATE ALKOXIDE COMPLEXES AND CERAMIC THIN-FILMS DERIVED THEREFROM - X-RAY STRUCTURES OF (H3CC(CH2-MU(3)-O)(CH2-MU-O)(2))(2)TI-4(OCH(CH3)(2))(10), (H3CCH2C(CH2-MU-3-O)(CH2-MU-O)(2))(2)TI-4(OCH(CH3)(2))(10), AND (H3CC(CH2-MU-O)(3))(2)ZR-4(MU-OCH(CH3)(2))(2)(OCH(CH3)(2))(8)(1) [J].

BOYLE, TJ ;

SCHWARTZ, RW ;

DOEDENS, RJ ;

ZILLER, JW .

INORGANIC CHEMISTRY, 1995, 34 (05) :1110-1120

[6] Reversible adduct formation between phosphines and triarylboron compounds [J].

Bradley, DC ;

Harding, IS ;

Keefe, AD ;

Motevalli, M ;

Zheng, DH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (20) :3931-3936

[7] Transition metal complexes of boron - synthesis, structure and reactivity [J].

Braunschweig, H ;

Colling, M .

COORDINATION CHEMISTRY REVIEWS, 2001, 223 :1-51

[8]

Britovsek GJP, 1999, ANGEW CHEM INT EDIT, V38, P428, DOI 10.1002/(SICI)1521-3773(19990215)38:4<428::AID-ANIE428>3.0.CO

[9]

2-3

[10] ORGANOBORANE-CARBON MONOXIDE REACTIONS . A NEW VERSATILE APPROACH TO SYNTHESIS OF CARBON STRUCTURES [J].

BROWN, HC .

ACCOUNTS OF CHEMICAL RESEARCH, 1969, 2 (03) :65-&

← 1 2 3 4 →