Tubular inorganic catalytic membrane reactors: advantages and performance in multiphase hydrogenation reactions

被引:56
作者
Centi, G
Dittmeyer, R
Perathoner, S
Reif, M
机构
[1] Dept Ind Chem & Engn Mat, I-98166 Messina, Italy
[2] DECHEMA EV, Karl Winnacker Inst Tech Chem, D-60486 Frankfurt, Germany
关键词
catalytic membrane; hydrogenation; structured reactor; nitrate; H2O2; chlorinated hydrocarbon;
D O I
10.1016/S0920-5861(03)00019-1
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The tubular inorganic catalytic membrane (TICM) reactor is a novel multiphase solution for advanced chemical or environmental technologies. The advantages of the use of this technology are discussed with reference to two types of applications: (i) C water remediation technologies by catalytic hydrogenation (nitrate removal and chlorinated hydrocarbon dehalogenation) and (ii) H2O2, synthesis by H-2 + O-2 reaction, both occurring over Pd-type catalysts supported over porous inorganic membranes. Some examples of the behaviour of these catalytic membranes are given in long-term tests in nitrate reduction, in chloroform dehalogenation and in H2O2 synthesis. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:139 / 149
页数:11
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