Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water

被引：145

作者：

Son, SU

Park, KH

Lee, YS

Kim, BY

Choi, CH

Lah, MS

Jang, YH

Jang, DJ

Chung, YK ^{[1
]}

机构：

[1] Seoul Natl Univ, Sch Chem, Seoul 151747, South Korea

[2] Seoul Natl Univ, Ctr Mol Catalysis, Seoul 151747, South Korea

[3] Kyungpook Natl Univ, Coll Nat Sci, Dept Chem, Taejon 702701, South Korea

[4] Hanyang Univ, Coll Sci, Dept Chem, Ansan 425791, South Korea

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 22期

关键词：

D O I：

10.1021/ic049514f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)(3)(2+) and Ru(terpy)(2)(2+), respectively, were synthesized. The complex, which is analogous to Ru(terpy)(2)(2+), exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were carried out.

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页码：6896 / 6898

页数：3

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