(4-vinylpyridine-styrene) copolymer as host polymer for chromophoric complexes with potential second order nonlinear optical properties

被引：7

作者：

Borbone, F

Caruso, U

De Maria, A

Fusco, M

Panunzi, B

Roviello, A

机构：

[1] Univ Naples Federico II, Dipartimento Chim, I-80126 Naples, Italy

[2] Univ Naples Federico II, Dipartimento Sci Alimenti, I-80055 Naples, Italy

来源：

MACROMOLECULAR SYMPOSIA | 2004年 / 218卷

关键词：

chromophoric metal complexes; grafted polymers; metal-polymer complexes; NLO; polymers;

D O I：

10.1002/masy.200451432

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of new metal containing polymers for second order nonlinear optics have been prepared by grafting Cu (II) and Pd (II) chromophoric complexes on a preformed (4-vinylpyridine-styrene) copolymeric backbone. The metallated polymers have been chemically and physically characterized. They show high glass transition temperatures, high thermal stability and good solubility. Their properties have been compared with analogous metallated poly(4-vinylpyridine) samples: variations in the polymeric backbone, as well as in ligands, metal, and metallation ratio, allow to tune their properties.

引用

页码：313 / 321

页数：9

共 4 条

[1]

BORBONE F, UNPUB EUR J INORG CH

[2] Synthesis, structure, and second-order nonlinear optical properties of copper(II) and palladium(II) acentric complexes with N-salicylidene-N′-aroylhydrazine tridentate ligands [J].