Modular assembly of two-dimensional metal-organic coordination networks at a metal surface

被引：251

作者：

Dmitriev, A

Spillmann, H

Lin, N

Barth, JV ^{[1
]}

Kern, K

机构：

[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

[2] Ecole Polytech Fed Lausanne, Inst Phys Nanostruct, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 23期

关键词：

coordination compounds; iron; nanomaterials; scanning tunneling microscopy; vacuum deposition;

D O I：

10.1002/anie.200250610

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Impressive iron networks: Two-dimensional metal-organic coordination networks have been prepared by the vacuum deposition of organic polytopic linkers and metal atoms on a copper surface. This unprecedented technique enabled the modular assembly of open Fe-carboxylate grids (see image, Fe atoms in green) that possess regularly spaced, identically shaped cavities. The structure and composition of the networks can be tuned by controlling the deposition parameters.

引用

页码：2670 / 2673

页数：4

共 53 条

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