Application of carbon adsorbents prepared from Brazilian-pine fruit shell for the removal of reactive orange 16 from aqueous solution: Kinetic, equilibrium, and thermodynamic studies

被引：157

作者：

Calvete, Tatiana ^{[1
]}

Lima, Eder C. ^{[1
]}

Cardoso, Natali F. ^{[1
]}

Vaghetti, Julio C. P. ^{[1
]}

Dias, Silvio L. P. ^{[1
]}

Pavan, Flavio A. ^{[2
]}

机构：

[1] Univ Fed Rio Grande do Sul, Inst Chem, BR-91501970 Porto Alegre, RS, Brazil

[2] UNIPAMPA, Bage, RS, Brazil

来源：

JOURNAL OF ENVIRONMENTAL MANAGEMENT | 2010年 / 91卷 / 08期

关键词：

Adsorption; Brazilian-pine fruit shell; Activated carbon; Reactive orange 16; Nonlinear isotherms; METHYLENE-BLUE BIOSORPTION; YELLOW PASSION-FRUIT; BASIC DYE REMOVAL; ACTIVATED CARBONS; STATISTICAL DESIGN; BATCH CONDITIONS; PECAN NUTSHELL; TOXIC METALS; AZO DYES; ADSORPTION;

D O I：

10.1016/j.jenvman.2010.03.013

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Activated (AC-PW) and non-activated (C-PW) carbonaceous materials were prepared from the Brazilian-pine fruit shell (Araucaria angustifolia) and tested as adsorbents for the removal of reactive orange 16 dye (RO-16) from aqueous effluents. The effects of shaking time, adsorbent dosage and pH on the adsorption capacity were studied. RO-16 uptake was favorable at pH values ranging from 2.0 to 3.0 and from 2.0 to 7.0 for C-PW and AC-PW, respectively. The contact time required to obtain the equilibrium using C-PW and AC-PW as adsorbents was 5 and 4 h at 298 K. respectively. The fractionary-order kinetic model provided the best fit to experimental data compared with other models. Equilibrium data were better fit to the Sips isotherm model using C-PW and AC-PW as adsorbents. The enthalpy and entropy of adsorption of RO-16 were obtained from adsorption experiments ranging from 298 to 323 K. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1695 / 1706

页数：12

共 61 条

[1]

[Anonymous], 1977, BASIC PRINCIPLES ORG

[2] Sorption of reactive dyes from aqueous solutions by ordered hexagonal and disordered mesoporous carbons [J].

Asouhidou, Despoina D. ;

Triantafyllidis, Kostas S. ;

Lazaridis, Nikolaos K. ;

Matis, Kostas A. ;

Kim, Seong-Su ;

Pinnavaia, Thomas J. .

MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 117 (1-2) :257-267

[3] Effects of structural and surface energetic heterogeneity properties of novel corn grain-based activated carbons on dye adsorption [J].

Balathanigaimani, M. S. ;

Shim, Wang-Geun ;

Park, Kwang Hyun ;

Lee, Jae-Wook ;

Moon, Hee .

MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 118 (1-3) :232-238

[4] Statistical design of experiments as a tool for optimizing the batch conditions to Cr(VI) biosorption on Araucaria angustifolia wastes [J].

Brasil, Jorge L. ;

Ev, Ricardo R. ;

Milcharek, Caroline D. ;

Martins, Lucas C. ;

Pavan, Flavio A. ;

dos Santos, Araci A., Jr. ;

Dias, Silvio L. P. ;

Dupont, Jairton ;

Norena, Caciano P. Zapata ;

Lima, Eder C. .

JOURNAL OF HAZARDOUS MATERIALS, 2006, 133 (1-3) :143-153

[5] Application of carbon adsorbents prepared from the Brazilian pine-fruit-shell for the removal of Procion Red MX 3B from aqueous solution-Kinetic, equilibrium, and thermodynamic studies [J].

Calvete, Tatiana ;

Lima, Eder C. ;

Cardoso, Natali F. ;

Dias, Silvio L. P. ;

Pavan, Flavio A. .

CHEMICAL ENGINEERING JOURNAL, 2009, 155 (03) :627-636

[6] Adsorption of anionic dyes on chitosan beads. 1. The influence of the chemical structures of dyes and temperature on the adsorption kinetics [J].

Cestari, AR ;

Vieira, EFS ;

dos Santos, AGP ;

Mota, JA ;

de Almeida, VP .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 280 (02) :380-386

[7] Adsorption of acid dyes by bamboo derived activated carbon [J].

Chan, L. S. ;

Cheung, W. H. ;

McKay, G. .

DESALINATION, 2008, 218 (1-3) :304-312

[8] Preparation and textural characterisation of activated carbon from vine shoots (Vitis vinifera) by H3PO4 -: Chemical activation [J].

Corcho-Corral, B. ;

Olivares-Marin, M. ;

Fernandez-Gonzalez, C. ;

Gomez-Serrano, V. ;

Macias-Garcia, A. .

APPLIED SURFACE SCIENCE, 2006, 252 (17) :5961-5966

[9] Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature [J].

Crini, Gregorio ;

Badot, Pierre-Marie .

PROGRESS IN POLYMER SCIENCE, 2008, 33 (04) :399-447

[10] Kinetic and calorimetric study of the adsorption of dyes on mesoporous activated carbon prepared from coconut coir dust [J].

de Souza Macedo, Jeremias ;

da Costa Junior, Nivan Bezerra ;

Almeida, Luis Eduardo ;

da Silva Vieira, Eunice Fragoso ;

Reinaldo Cestari, Antonio ;

de Fatima Gimenez, Iara ;

Villarreal Carreno, Neftali Lenin ;

Silva Barreto, Ledjane .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 298 (02) :515-522

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