Preparation of room-temperature ionic liquids by neutralization of 1,1,3,3-tetramethylguanidine with acids and their use as media for Mannich reaction

被引:105
作者
Gao, HX [1 ]
Han, BX [1 ]
Li, JC [1 ]
Jiang, T [1 ]
Liu, ZM [1 ]
Wu, WZ [1 ]
Chang, YH [1 ]
Zhang, JM [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
guanidine; ionic liquids; Mannich reaction;
D O I
10.1081/SCC-200028532
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
New room-temperature ionic liquids (ILs) were prepared by neutralization of 1,1,3,3-tetramethylguanidine with different acids under ambient condition. The density, viscosity, decomposition temperature, electronic conductivity, and miscibility with some commonly used solvents were determined. As an example of the applications of the new ILs, the reaction
引用
收藏
页码:3083 / 3089
页数:7
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