Hydrogen storage properties of new ternary system alloys:: La2MgNi9, La5Mg2Ni23, La3MgNi14

被引：614

作者：

Kohno, T

Yoshida, H

Kawashima, F

Inaba, T

Sakai, I

Yamamoto, M

Kanda, M

机构：

[1] Toshiba Corp, Power Supply Mat & Devices Res Labs, Ctr Corp Res & Dev, Shinagawa Ku, Tokyo 1400004, Japan

[2] Toshiba Corp, Battery Technol Dev Div, Display Devices & Components Co, Shinagawa Ku, Tokyo 1400004, Japan

[3] Toshiba Corp, Mat & Components Dev Grp, Mat & Components Dev Dept, Display Devices & Components Co,Isogo Ku, Yokohama, Kanagawa 2358522, Japan

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2000年 / 311卷 / 02期

关键词：

hydrogen storage materials; electrode materials; crystal structure; X-ray diffraction; electrochemical reactions;

D O I：

10.1016/S0925-8388(00)01119-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrogen storage properties of the new ternary system alloys, La2MgNi9, La5Mg2Ni23, La3MgNi14, were investigated. As a result, the negative electrode of the La5Mg2Ni23 alloy (La0.7ME0.3Ni2.8Co0.5) showed a large discharge capacity (410 mAh/g), 1.3 times larger than that of AB(5) type alloys. These ternary system alloys were found to be mainly composed of stacked AB(5) and AB(2) structure subunits in a superstructure arrangement. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：L5 / L7

页数：3

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