Highly conducting water-soluble polythiophene derivatives

被引：122

作者：

Chayer, M ^{[1
]}

Faid, K ^{[1
]}

Leclerc, M ^{[1
]}

机构：

[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada

来源：

CHEMISTRY OF MATERIALS | 1997年 / 9卷 / 12期

关键词：

D O I：

10.1021/cm970238v

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Water-soluble sodium poly(2-(3-thienyloxy)ethanesulfonate) and sodium poly(2-(4-methyl-3-thienyloxy)ethanesulfonate) have been synthesized. The sulfonic acid form of these new polymers has revealed a self-acid-doping reaction that leads to stable, highly conducting (0.5-5 S/cm) materials together with low absorption in the visible range. This process is reversible, and upon deprotonation, the insulating and dark polymers are recovered. The high doping and conductivity levels seem to be related to the relatively low oxidation potentials (0.44-0.50 V vs Ag/AgCl) of these polymers, which allows an almost complete (reversible) oxidation reaction in air (oxygen), catalyzed by the presence of the sulfonic acid moiety.

引用

页码：2902 / 2905

页数：4

共 31 条

[1] STRUCTURE AND DOPING LEVEL OF THE SELF-ACID-DOPED CONJUGATED CONDUCTING POLYMERS - POLY[N-(3'-THIENYL)ALKANESULFONIC ACID]S [J].

CHEN, SA ;

HUA, MY .

MACROMOLECULES, 1993, 26 (25) :7108-7110

[2] POLY(3,3'-DIBUTOXY-2,2'-BITHIOPHENE) - A NEW HIGHLY CONJUGATED POLYTHIOPHENE DERIVATIVE [J].

CLOUTIER, R ;

LECLERC, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (17) :1194-1195

[3] STRUCTURE PROPERTY RELATIONSHIPS IN ALKOXY-SUBSTITUTED POLYTHIOPHENES [J].

DAOUST, G ;

LECLERC, M .

MACROMOLECULES, 1991, 24 (02) :455-459

[4]

DIAZ AF, 1995, PHYSICAL ELECTROCHEM, P555

[5] Towards a theoretical design of thermochromic polythiophenes [J].

DiCesare, N ;

Belletete, M ;

Durocher, G ;

Leclerc, M .

CHEMICAL PHYSICS LETTERS, 1997, 275 (5-6) :533-539

[6] DESIGN OF NOVEL ELECTROACTIVE POLYBITHIOPHENE DERIVATIVES [J].

FAID, K ;

CLOUTIER, R ;

LECLERC, M .

MACROMOLECULES, 1993, 26 (10) :2501-2507

[7]

FAID K, 1996, J CHEM SOC CHEM COMM, P2761

[8]

FELDHUES M, 1989, SYNTHETIC MET, V28, pC487, DOI 10.3724/SP.J.1001.2011.03729

[9]

FELDHUES M, 1992, Patent No. 5093033

[10]

Han C. C., 1993, U.S. Patent, Patent No. [5,185,100, 5185100]

← 1 2 3 4 →