Selective oxidation of sulfides to sulfoxides using IBX-esters

被引：36

作者：

Koposov, AY ^{[1
]}

Zhdankin, VV ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Duluth, MN 55812 USA

来源：

SYNTHESIS-STUTTGART | 2005年 / 01期

关键词：

hypervalent iodine; IBX-esters; sulfides; sulfoxides;

D O I：

10.1055/s-2004-834873

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

IBX-esters (esters of 2-iodoxybenzoic acid) are convenient hypervalent iodine reagents for the clean and selective oxidation of organic sulfides to sulfoxides. This reaction proceeds without over-oxidation to sulfones and is compatible with the presence of the hydroxy group, double bond, phenol ether, benzylic carbon, and various substituted phenyl rings in the molecule of the substrate.

引用

收藏

页码：22 / 24

页数：3

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