Generic density functional for electric double layers in a molecular solvent

被引：56

作者：

Biben, T ^{[1
]}

Hansen, JP ^{[1
]}

Rosenfeld, Y ^{[1
]}

机构：

[1] Ecole Normale Super Lyon, Phys Lab, CNRS, URA 1325, F-69364 Lyon 07, France

来源：

PHYSICAL REVIEW E | 1998年 / 57卷 / 04期

关键词：

D O I：

10.1103/PhysRevE.57.R3727

中图分类号：

O35 [流体力学]; O53 [等离子体物理学];

学科分类号：

070204 ; 080103 ; 080704 ;

摘要：

A simple, generic density functional for a statistical description of electric double layers in a molecular solvent is presented. The functional, which may be adapted to any geometry, is applied to the case of planar geometry, to pinpoint the limitations of the usual continuum description of the solvent.

引用

页码：R3727 / R3730

页数：4

共 19 条

[1] SOLVATION FORCES IN A MODEL FLUID MIXTURE OF IONS AND DIPOLES
AUGOUSTI, AT
RICKAYZEN, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1984, 80 : 141 - 156
[2] MIXTURES OF HARD IONS AND DIPOLES AGAINST A CHARGED WALL - THE ORNSTEIN-ZERNIKE EQUATION, SOME EXACT RESULTS, AND THE MEAN SPHERICAL APPROXIMATION
BLUM, L
HENDERSON, D
[J]. JOURNAL OF CHEMICAL PHYSICS, 1981, 74 (03) : 1902 - 1910
[3] Steric effects in electrolytes: A modified Poisson-Boltzmann equation
Borukhov, I
Andelman, D
Orland, H
[J]. PHYSICAL REVIEW LETTERS, 1997, 79 (03) : 435 - 438
[4] THE STRUCTURE OF ELECTROLYTES AT CHARGED SURFACES - ION-DIPOLE MIXTURES
CARNIE, SL
CHAN, DYC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (06) : 2949 - 2957
[5] A Contribution to the Theory of Electrocapillarity
Chapman, David Leonard
[J]. PHILOSOPHICAL MAGAZINE, 1913, 25 (148) : 475 - 481
[6] THE DENSITY AND POLARIZATION OF AN ION-DIPOLE-ELECTROLYTE NEAR A CHARGED WALL
DIAZHERRERA, E
FORSTMANN, F
[J]. JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (22) : 9005 - 9017
[7] EVANS R, 1991, INHOMOGENEOUS FLUIDS
[8] Oscillatory surface forces: A test of the superposition approximation
Frink, LJD
vanSwol, F
[J]. JOURNAL OF CHEMICAL PHYSICS, 1996, 105 (07) : 2884 - 2890
[9] Gouy M., 1910, J. Phys. Theor. Appl, V9, P457, DOI DOI 10.1051/JPHYSTAP:019100090045700
[10] FORCES BETWEEN SURFACES IN ELECTROLYTE-SOLUTIONS
GRIMSON, MJ
RICKAYZEN, G
[J]. CHEMICAL PHYSICS LETTERS, 1982, 86 (01) : 71 - 75

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