Building off the back of chelators: Synthesis of 3,3''-bis(4-methylphenyl)-2,2':6',2''-terpyridine

被引：13

作者：

Benniston, AC

机构：

[1] Chemistry Department, University of Glasgow

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 47期

关键词：

D O I：

10.1016/S0040-4039(97)10167-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Using an adaptation of the Jameson method for the synthesis of 2,2':6',2''-terpyridine (terpy), a ditolyl-functionalised ligand has been prepared in which the substituted groups are located in the highly unusual 3,3 '' position. The new ligand represents an attempt to develop terpy-based systems with di-functionality that emerges from the 'back side' of the chelator. (C) 1997 Elsevier Science Ltd.

引用

页码：8279 / 8282

页数：4

共 12 条

[1] PRONOUNCED ELECTRONIC COUPLING IN RIGIDLY CONNECTED N,C,N-COORDINATED DIRUTHENIUM COMPLEXES OVER A DISTANCE OF UP TO 20-ANGSTROM [J].

BELEY, M ;

CHODOROWSKIKIMMES, S ;

COLLIN, JP ;

LAINE, P ;

LAUNAY, JP ;

SAUVAGE, JP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (17) :1775-1778

[2] DYNAMICS OF CHARGE-TRANSFER AND RECOMBINATION IN A COVALENTLY-LINKED, FACE-TO-FACE ELECTRON DONOR-ACCEPTOR COMPLEX [J].

BENNISTON, AC ;

HARRIMAN, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (25) :11531-11537

[3] Cation chelating [2]catenanes and cyclophanes based on 2,2'-bipyridine. [J].

Benniston, AC ;

Mackie, PR ;

Harriman, A .

TETRAHEDRON LETTERS, 1997, 38 (20) :3577-3580

[4]

BENNISTON AC, 1994, ANGEW CHEM INT EDIT, V33, P1884, DOI 10.1002/anie.199418841

[5]

CargillThompson A. M. W., 1997, Coord. Chem. Rev, V160, P1, DOI [10.1016/S0010-8545(96)01283-0, DOI 10.1016/S0010-8545(96)01283-0]

[6] A CONVENIENT, HIGH-YIELD SYNTHESIS OF 2,2'-6',2'-TERPYRIDINE AND ITS IRON(II) COMPLEX [J].

CONSTABLE, EC ;

WARD, MD ;

CORR, S .

INORGANICA CHIMICA ACTA, 1988, 141 (02) :201-203

[7] THE COORDINATION CHEMISTRY OF 2,2'-6',2''-TERPYRIDINE AND HIGHER OLIGOPYRIDINES [J].

CONSTABLE, EC .

ADVANCES IN INORGANIC CHEMISTRY, 1986, 30 :69-121

[8] AN IMPROVED, 2-STEP SYNTHESIS OF 2,2'-6',2''-TERPYRIDINE [J].

JAMESON, DL ;

GUISE, LE .

TETRAHEDRON LETTERS, 1991, 32 (18) :1999-2002

[9] SYNTHESIS USING PYRIDINIUM SALTS .5. SPECIFIC SYNTHESIS OF PYRIDINES AND OLIGOPYRIDINES [J].

KROHNKE, F .

SYNTHESIS-STUTTGART, 1976, (01) :1-24

[10] SYNTHESIS OF 2,6-DISUBSTITUTED PYRIDINES, POLYPYRIDINYLS, AND ANNULATED PYRIDINES [J].

POTTS, KT ;

CIPULLO, MJ ;

RALLI, P ;

THEODORIDIS, G .

JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (16) :3027-3038

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