Alkali-metalated forms of thiacalix[4]arenes

被引：22

作者：

Zeller, Jurgen ^{[1
]}

Radius, Udo ^{[1
]}

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 23期

关键词：

D O I：

10.1021/ic0613311

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The alkali metal salts [TCALi(4)] (1), [TCANa(4)] (2), and [TCALK(4)] (3) of fully deprotonated p-tert-butyltetrathiacalix-[4] arene (H(4)TCA) are readily available from the reactions of thiacalix[4] arene and n-BuLi, NaH, or KH as deprotonating reagents. Crystals of the sodium salts 2 and the potassium salt 3 suitable for X-ray diffraction were obtained in the form of the pyridine solvates [(TCA)(2)Na-8 center dot 8py] (2 center dot 8py) and [(TCA)(2)K-8 center dot 8py] (3 center dot 8py). These molecules are dimers in the solid state but are structurally not related. In addition, the reaction of H4TCA and lithium hydroxide afforded the structurally characterized complex [(TCA) Li-5(OH)center dot 4THF] (4). The molecular structure of 4 as well as the structures of 2, 8py and 3, 8py reveal a close relationship to the corresponding alkali metal salts of the calix[4] arenes.

引用

页码：9487 / 9492

页数：6

共 55 条

[1]

Asfari Z, 2001, ANGEW CHEM INT EDIT, V40, P721, DOI 10.1002/1521-3773(20010216)40:4<721::AID-ANIE7210>3.0.CO

[2]

2-G

[3] A unique rare-earth cluster within a calixarene sandwich: Parallels in the chemistry of cyclosiloxanes and calixarenes [J].

Bilyk, A ;

Hall, AK ;

Harrowfield, JM ;

Hosseini, MW ;

Skelton, BW ;

White, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2000, 53 (11-12) :895-898

[4]

Bilyk A, 2000, EUR J INORG CHEM, P823

[5] Systematic structural coordination chemistry of p-tert-butyltetrathiacalix[4]arene:: 1.: Group 1 elements and congeners [J].

Bilyk, A ;

Hall, AK ;

Harrowfield, JM ;

Hosseini, MW ;

Skelton, BW ;

White, AH .

INORGANIC CHEMISTRY, 2001, 40 (04) :672-686

[6] CRYSTALLIZATION AND STRUCTURE OF ((H53C44O43-)[LI-6(+)(NH3)(2)]((O4C44H53)-O-3-)), AN EDGE-SHARED LI-6(+) DOUBLE TETRAHEDRON BETWEEN CALIX[4]ARENETRIANION HALF-SHELLS - ANOTHER SELF-ORGANIZED AND PIPOPHILICALLY-WRAPPED POLYION AGGREGATE [J].

BOCK, H ;

JOHN, A ;

NATHER, C ;

HAVLAS, Z .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (36) :9367-9368

[7] CALIXARENES, MACROCYCLES WITH (ALMOST) UNLIMITED POSSIBILITIES [J].

BOHMER, V .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07) :713-745

[8]

Bohmer V, 1997, LIEBIGS ANN-RECL, P2019

[9]

Bohmer V., 1995, ANGEW CHEM, V107, P785, DOI DOI 10.1002/ANGE.19951070704

[10] Synthesis and X-ray structures of tetralithium derivatives of tert-butylcalix[4]arene containing unique Li-O cores based on a square-pyramidal geometry [J].

Davidson, MG ;

Howard, JAK ;

Lamb, S ;

Lehmann, CW .

CHEMICAL COMMUNICATIONS, 1997, (17) :1607-1608

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