The sorption of heavy-metal cations from EDTA complexes on acrylamide resins having oligo(ethyleneamine) moieties

被引:41
作者
Matejka, Z [1 ]
Zitkova, Z [1 ]
机构
[1] Inst Chem Technol, Power Engn Dept, CR-16628 Prague, Czech Republic
关键词
chelated heavy metals; EDTA complexes; chelating exchangers; heavy-metal recovery;
D O I
10.1016/S1381-5148(97)00052-7
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Removal of heavy metals from solutions containing a powerful chelator EDTA and the separation of heavy metals from this anionic ligand are important for the efficient treatment of waste water and for recovery and reuse of heavy metals. The optimum working conditions of acrylamide sorbents having oligo(ethyleneamine) moieties for uptake of chelated heavy metals (i.e. molar ratio (EDTA:Me)(solution), sorption kinetics and solution flow-rate, concentration of heavy metal and pH value in the loading solution, presence of Mg2+ or Ca2+ cations), for resin regeneration and for separation of EDTA were investigated. Development resins having OEA moieties and some commercially available exchangers were studied and compared for this application.
引用
收藏
页码:81 / 88
页数:8
相关论文
共 8 条
[1]  
Clifford D., 1983, REACT POLYM, V1, P77, DOI DOI 10.1016/0167-6989(83)90040-5
[2]  
COURDUVELIS C, 1982, P AES 4 C ADV POLL C
[3]  
DUDZINSKA MR, 1992, REACT POLYM, V16, P71
[4]  
KORTLY S, 1985, HDB CHEM EQUILIBRIA, P59
[5]  
KRAUSS D, 1982, PLASTE KAUTSCH, V29, P449
[6]  
Martell A. E., 1988, DETERMINATION USE ST
[7]  
PICK ME, 1979, 4660 RDBN CENTR EL G
[8]  
SZABADKA O, 1979, ACTA CHIM HUNG, V99, P363