Oriented Arrays of Graphene in a Polymer Matrix by in situ Reduction of Graphite Oxide Nanosheets

被引:135
作者
Ansari, Seema [1 ]
Kelarakis, Antonios [1 ]
Estevez, Luis [1 ]
Giannelis, Emmanuel P. [1 ]
机构
[1] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA
关键词
graphite oxide; graphene; nanocomposites; Nafion; ELECTRONIC CONDUCTIVITY; NANOCOMPOSITES; MEMBRANES; SHEETS; NAFION;
D O I
10.1002/smll.200900765
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphite oxide-Nafion hybrids with a high degree of alignment are cast from aqueous solution in the absence of any external field and reduced in situ by exposure to hydrazine to produce graphene-Nafion hybrids. Dramatic enhancement of electrical conductivity indicates sufficient accessibility of the inorganic nanosheets to the reducing agent, through the nanochannels formed by the polymeric ionic domains. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:205 / 209
页数:5
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