Lanthanide(III) complexes of a pyridine N-oxide analogue of DOTA:: exclusive M isomer formation induced by a six-membered chelate ring

被引:34
作者
Polásek, M
Rudovsky, J
Hermann, P
Lukes, I
Vander Else, L
Muller, RN
机构
[1] Charles Univ, Dept Inorgan Chem, CR-12840 Prague 2, Czech Republic
[2] Univ Mons, Dept Organ Chem, NMR Lab, B-7000 Mons, Belgium
关键词
D O I
10.1039/b409996f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The presence of a six-membered chelate ring involving a pyridine N-oxide moiety induces exclusive M isomer formation throughout the whole lanthanide series endowed with a fast water exchange in the case of the Gd(III) complex.
引用
收藏
页码:2602 / 2603
页数:2
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