Synthesis and characterisation of tetrazole compounds: 3 series of new ligands representing versatile building blocks for iron(II) spin-crossover compounds

被引：46

作者：

Grunert, CM

Weinberger, P

Schweifer, J

Hampel, C

Stassen, AF

Mereiter, K

Linert, W

机构：

[1] Vienna Univ Technol, Inst Appl Synt Chem, A-1060 Vienna, Austria

[2] Johannes Gutenberg Univ Mainz, Inst Inorgan & Analyt Chem, D-55099 Mainz, Germany

[3] Gessell Forderung Med Bio & Umwelttechnol E V, D-06132 Halle An Der Saale, Germany

[4] Delft Univ Technol, Kavli Inst Nanosci, NL-2628 CJ Delft, Netherlands

[5] Vienna Univ Technol, Inst Chem Technol & Analyt, A-1060 Vienna, Austria

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2005年 / 733卷 / 1-3期

关键词：

tetrazole; crystal structure; FTIR spectroscopy; NMR spectroscopy;

D O I：

10.1016/j.molstruc.2004.07.036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New tetrazole compounds were synthesized and characterised by NMR and FTIR spectroscopy as well as by single crystal X-ray diffraction. We present in this paper mono- and ditetrazoles, which represent a versatile class of building blocks for the formation of mononuclear iron(H) complexes with monotetrazoles as terminal ligands as well as iron(H) coordination polymers with ditetrazoles as bridging ligands. Especially, the series of alpha,w-bis[tetrazol-1-yl]-alkanes open the field of fascinating supramolecular structures with spin transition properties. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：41 / 52

页数：12

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