The ins and outs of molecular encapsulation

被引：153

作者：

Palmer, LC

Rebek, J

机构：

[1] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA

[2] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2004年 / 2卷 / 21期

关键词：

D O I：

10.1039/b412510j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Molecular capsules can act as hosts for appropriate guests, and bring them into well-defined nanoenvironments. Various spectroscopic methods have been used to deduce the mechanism of guest exchange in such systems. Generally, the guests get in and out of capsules through the opening and closing of host "flaps" but smaller capsules can exchange simply by dissociation of the host subunits.

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页码：3051 / 3059

页数：9

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