Understanding reactivity patterns of radical cations

被引：383

作者：

Schmittel, M ^{[1
]}

Burghart, A ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1997年 / 36卷 / 23期

关键词：

electron transfer; kinetics; radical ions; reaction mechanisms; thermodynamics;

D O I：

10.1002/anie.199725501

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Over the last 15 years electron transfer activation has emerged as a valuable concept for accomplishing novel reactions and has found widespread application in the selective transformation of increasingly complex molecules. This review presents in a conceptualized manner the vast number of radical cation reactions obtained after chemical, electrochemical, and photo-induced one-electron oxidation. To familiarize the reader with the concepts of electron transfer a simple and straightforward classification of radical cation reactions has been devised to allow the presentation of a manifold of reactions in a readily understandable manner. Whenever possible, thermochemical and kinetic data are provided. © WILEY-VCH Verlag GmbH, D-69451 Weinheim, 1997.

引用

页码：2550 / 2589

页数：40

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