Experimental evidence for crossover to mean-field tricritical behavior in a concentrated salt solution

被引:66
作者
Anisimov, MA [1 ]
Jacob, J
Kumar, A
Agayan, VA
Sengers, JV
机构
[1] Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA
[2] Univ Maryland, Dept Chem Engn, College Pk, MD 20742 USA
[3] Indian Inst Sci, Dept Phys, Bangalore 560012, Karnataka, India
关键词
D O I
10.1103/PhysRevLett.85.2336
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We have discovered a mean-field multicritical point on the critical locus in an aqueous solution of 3-methylpyridine and sodium bromide. Light-scattering measurements indicate Ising-like asymptotic critical behavior at the lower salt concentrations. However, the temperature range of Ising critical behavior shrinks with increasing salt concentration and the critical behavior becomes mean-field-like at a concentration of about 17% mass fraction of NaBr. Emergence of a new characteristic length scale diverging at this point and a simultaneous pronounced increase in the background scattering suggests mean-field tricritical behavior associated with the formation of a microheterogeneous phase due to clustering of ions and molecules.
引用
收藏
页码:2336 / 2339
页数:4
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