A density functional theory study of π-facial stereoselectivity in intramolecular Diels-Alder reactions

被引：21

作者：

Paddon-Row, MN ^{[1
]}

Sherburn, MS

机构：

[1] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

[2] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 22期

关键词：

D O I：

10.1039/b006486f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

B3LYP/6-31G(d) theory has been used to construct a transition structure model which correctly accounts for the observed pi -diastereofacial selectivity in intramolecular Diels-Alder reactions induced by allylic substituents attached to the diene.

引用

页码：2215 / 2216

页数：2

共 13 条

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