Synthesis of Microporous Carbon Foams as Catalyst Supports

被引:33
作者
Glenk, Friedrich [1 ]
Knorr, Tilman [1 ]
Schirmer, Matthias [1 ]
Guetlein, Stefan [1 ]
Etzold, Bastian J. M. [1 ]
机构
[1] Univ Erlangen Nurnberg, Chair Chem React Engn, D-91058 Erlangen, Germany
关键词
Carbide-derived carbon; CDC method; Foams; Microporous carbon; CARBIDE-DERIVED CARBONS; HYDROGEN STORAGE; ACTIVATED CARBON; MONOLITHS; NITROBENZENE; POROSITY; REACTOR;
D O I
10.1002/ceat.201000005
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Microporous carbon foams were synthesized as structured catalyst supports by the carbide-derived carbon (CDC) method. The self-supporting foams showed a narrow pore size distribution which seems to induce shape-selective effects during reactions. The applicability of these materials as supports for active metals was tested in a hydrogenation reaction of different olefins with a CDC powder wet impregnated with platinum.
引用
收藏
页码:698 / 703
页数:6
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共 25 条
  • [1] Concept study: structured trickling bed reactor
    Bauer, Tobias
    Haase, Stefan
    Lange, Ruediger
    [J]. CHEMIE INGENIEUR TECHNIK, 2009, 81 (07) : 989 - 994
  • [2] Ceramic foam monoliths as catalyst carriers. 1. Adjustment and description of the morphology
    Buciuman, FC
    Kraushaar-Czarnetzki, B
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (09) : 1863 - 1869
  • [3] Starbons: New starch-derived mesoporous carbonaceous materials with tunable properties
    Budarin, Vitaly
    Clark, James H.
    Hardy, Jeffrey J. E.
    Luque, Rafael
    Milkowski, Krzysztof
    Tavener, Stewart J.
    Wilson, Ashley J.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (23) : 3782 - 3786
  • [4] Carbonized wood monoliths - Characterization
    Byrne, CE
    Nagle, DC
    [J]. CARBON, 1997, 35 (02) : 267 - 273
  • [5] Synthesis, structure and porosity analysis of microporous mesoporous carbon derived from zirconium carbide
    Dash, RK
    Yushin, G
    Gogotsi, Y
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 86 (1-3) : 50 - 57
  • [6] Nanoporous carbide-derived carbon with tunable pore size
    Gogotsi, Y
    Nikitin, A
    Ye, HH
    Zhou, W
    Fischer, JE
    Yi, B
    Foley, HC
    Barsoum, MW
    [J]. NATURE MATERIALS, 2003, 2 (09) : 591 - 594
  • [7] Tailoring of nanoscale porosity in carbide-derived carbons for hydrogen storage
    Gogotsi, Y
    Dash, RK
    Yushin, G
    Yildirim, T
    Laudisio, G
    Fischer, JE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (46) : 16006 - 16007
  • [8] Carbon coatings on silicon carbide by reaction with chlorine-containing gases
    Gogotsi, YG
    Jeon, ID
    McNallan, MJ
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (09) : 1841 - 1848
  • [9] Functional carbonaceous materials from hydrothermal carbonization of biomass: an effective chemical process
    Hu, Bo
    Yu, Shu-Hong
    Wang, Kan
    Liu, Lei
    Xu, Xue-Wei
    [J]. DALTON TRANSACTIONS, 2008, (40) : 5414 - 5423
  • [10] Synthesis of hierarchically porous carbon monoliths with highly ordered microstructure and their application in rechargeable lithium batteries with high-rate capability
    Hu, Yong-Sheng
    Adelhelm, Philipp
    Smarsly, Bernd M.
    Hore, Sarmimala
    Antonietti, Markus
    Maier, Joachim
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (12) : 1873 - 1878