On the presence of branching in polyaniline chains

被引：3

作者：

Matnishyan, A. A. ^{[1
]}

Akhnazaryan, T. L. ^{[1
]}

机构：

[1] Yerevan Res Inst Opt Phys Measurements, Yerevan 375031, Armenia

来源：

POLYMER SCIENCE SERIES B | 2007年 / 49卷 / 5-6期

关键词：

D O I：

10.1134/S1560090407050089

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of polyaniline via the oxidation of aniline with ammonium bisulfate in water and formic acid was monitored potentiometrically by following the yield and changes in the electric conductivity of the polymer. Three basic stages of the process were determined, including the buildup of oligomeric quinone imines, chain propagation via aniline addition of quinone imime groups, and postpolymerization. The oligomeric intermediate products, substituted quinone imines, were isolated. On the basis of IR and NMR data, the presence of tri- and tetrasubstituted aromatic groups and phenazine structural units in the polyaniline chain was revealed.

引用

页码：139 / 142

页数：4

共 18 条

[1]

BERLIN AA, 1967, IAN SSSR KH, P225

[2] Electrochemistry of conductive polymers XXIII: polyaniline growth studied by electrochemical quartz crystal microbalance measurements [J].

Cui, SY ;

Park, SM .

SYNTHETIC METALS, 1999, 105 (02) :91-98

[3]

Dyer J.R., 1970, APPL ABSORPTION SPEC

[4] Radicalsas intermediary stage in chemical reactions (VI. Announcement on amin oxydation). [J].

Goldschmidt, S ;

Wurzschmitt, B .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1922, 55 :3216-3220

[5] Conducting polymers prepared by oxidative polymerization: Polyaniline [J].

Gospodinova, N ;

Terlemezyan, L .

PROGRESS IN POLYMER SCIENCE, 1998, 23 (08) :1443-1484

[6]

JOZEFOWICZ M, 1965, CR HEBD ACAD SCI, V260, P2037

[7] Synthesis and characterization of o-phenylenediamine and xylidine copolymers [J].

Li, XG ;

Huang, MR ;

Yang, YL .

POLYMER, 2001, 42 (09) :4099-4107

[8] Oligomers and isomers: new horizons in poly-anilines [J].

MacDiarmid, AG ;

Zhou, Y ;

Feng, J .

SYNTHETIC METALS, 1999, 100 (01) :131-140

[9] Effect of elevated temperature on the reactivity and structure of polyanihne [J].

Mathew, R ;

Yang, DL ;

Mattes, BR ;

Espe, MP .

MACROMOLECULES, 2002, 35 (20) :7575-7581

[10]

MATNISHYAN AA, 2004, POLYM SCI SER A, V46, P1320

← 1 2 →