The synthesis of phycopsisenone, a new phenolic secondary metabolite from the sponge Phycopsis sp.

被引：9

作者：

Kad, GL ^{[1
]}

Singh, V ^{[1
]}

Khurana, A ^{[1
]}

Singh, J ^{[1
]}

机构：

[1] Punjab Univ, Dept Chem, Chandigarh 160014, India

来源：

JOURNAL OF NATURAL PRODUCTS | 1998年 / 61卷 / 02期

关键词：

D O I：

10.1021/np970394g

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

A short first total synthesis of phycopsisenone (1) utilizing microwave irradiation-induced aldol condensation and TiCl4-catalyzed reaction of silyl enol ether (3) with acetone as key steps has been achieved in 29.4% overall yield.

引用

页码：297 / 298

页数：2

共 4 条

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[2] MARINE NATURAL-PRODUCTS - METABOLITES OF MARINE-ALGAE AND HERBIVOROUS MARINE MOLLUSKS
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[3] USE OF 1,8-DIAZABICYCLO[5.4.0]UNDEC-7-ENE IN PREPARATION OF TRIMETHYLSILYL ENOL ETHERS AND TRIMETHYLSILYLACETYLENES
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[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1981, 54 (10) : 3229 - 3230
[4] PHYCOPSISENONE, A NEW PHENOLIC SECONDARY METABOLITE FROM THE SPONGE PHYCOPSIS SP
VENKATESWARLU, Y
BIABANI, MAF
RAO, JV
[J]. JOURNAL OF NATURAL PRODUCTS-LLOYDIA, 1995, 58 (02): : 269 - 270

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