Research on nanophase MnO2 for electrochemical supercapacitor

被引:13
作者
Zhang, BH [1 ]
Zhang, N [1 ]
机构
[1] Harbin Engn Univ, Dept Chem Engn, Harbin 150001, Peoples R China
关键词
supercapacitor; MnO2; electrode; electrode material; specific capacitance; cycle life;
D O I
10.3866/PKU.WHXB20030323
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The nanophase MnO2 was synthesized by solid-phase reaction as electrode material for electrochemical supercapacitor and the MnO2 electrode was tested by cyclic voltammetry(CV), electrochemical impedance spectrometry (EIS) and constant charge-discharge curves. The result shows that MnO2 electrode has good performance of faradic pseudocapacitance in 1mol . L-1 KOH between -0.1 and 0.6 V (vs Hg/HgO). The electrode can provide a specific capacitance of 240.25 to 325. 21 F . g(-1) at different current densities. After 5000 cycles of constant charge-discharge the capacitance reduces no more than 10%.
引用
收藏
页码:286 / 288
页数:3
相关论文
共 8 条
[1]  
CONWAY BE, 1999, ELECTROCHEMICAL SUPE, P9
[2]  
HU CC, 2002, ELECTROCHEM COMMUN, P105
[3]  
LI J, 1999, CHINESE J APPL CHEM, V16, P103
[4]   Characterization of sol-gel-derived cobalt oxide xerogels as electrochemical capacitors [J].
Lin, C ;
Ritter, JA ;
Popov, BN .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (12) :4097-4103
[5]   Porous nickel oxide/nickel films for electrochemical capacitors [J].
Liu, KC ;
Anderson, MA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) :124-130
[6]   Novel electrode materials for thin-film ultracapacitors: Comparison of electrochemical properties of sol-gel-derived and electrodeposited manganese dioxide [J].
Pang, SC ;
Anderson, MA ;
Chapman, TW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (02) :444-450
[7]  
VENKAT S, 1997, J ELECTROCHEM SOC, V144, pL120
[8]  
WANG GQ, 2000, ELECT COMPONNETS MAT, V19, P15