The infrared spectrum of the benzoyl cation

被引：22

作者：

Oomens, J

Bakker, JM

Sartakov, BG

Meijer, G

von Helden, G

机构：

[1] FOM, Inst Plasma Phys Rijnhuizen, Mol Dynam Grp, NL-3439 MN Nieuwegein, Netherlands

[2] Catholic Univ Nijmegen, Dept Mol & Laser Phys, NL-6525 ED Nijmegen, Netherlands

[3] Max Planck Gesell, Fritz Haber Inst, Dept Mol Phys, D-14195 Berlin, Germany

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 367卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(02)01799-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vibrational spectrum of the gas phase benzoyl cation (C6H5CO+) in the 500-2500 cm(-1) range is presented. Vapor phase benzoic acid is photolyzed/photoionized using an ArF excimer laser and the resulting ionic fragments are stored in a quadrupole ion trap. The benzoyl cation is subsequently isolated and its infrared spectrum is recorded through multiple photon dissociation spectroscopy with a free electron laser. Density functional calculations predict a C-2v structure for the benzoyl cation, which is in good agreement with the observed spectrum. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：576 / 580

页数：5

共 23 条

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