Stilbazolium dyes containing rare-earth ions

被引:7
作者
Binnemans, K [1 ]
机构
[1] Katholieke Univ Leuven, Dept Chem, Coordinat Chem Div, B-3001 Heverlee, Belgium
关键词
lanthanides; rare earths; hemicyanine; stilbazolium; dye stuff; solvatochromism;
D O I
10.1016/S0925-8388(00)00618-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The synthesis, thermal and spectroscopic properties of 28 rare-earth containing stilbazolium dyes are described. The complexes are prepared by reaction of the corresponding stilbazolium bromide (hemicyanine bromide) with a lanthanide salt and with a pyrazolone or a P-diketone. The bromide is replaced by a tetrakis pyrazolonato or by a tetrakis beta-diketonato lanthanide(III) counter ion. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:125 / 131
页数:7
相关论文
共 19 条
[1]   Solvatochromism of lanthanide complexes containing the hemicyanine chromophore [J].
Binnemans, K ;
Bex, C ;
Venard, A ;
De Leebeeck, H ;
Görller-Walrand, C .
JOURNAL OF MOLECULAR LIQUIDS, 1999, 83 (1-3) :283-294
[2]   Ionic liquid crystals with hemicyanine chromophores [J].
Binnemans, K ;
Bex, C ;
Van Deun, R .
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 1999, 35 (1-2) :63-73
[3]  
Bruce D. W., 1994, Advanced Materials for Optics and Electronics, V4, P293, DOI 10.1002/amo.860040409
[4]  
Carnall W. T., 1979, Handbook on the Physics and Chemistry of Rare-earths, Vol.3. Non-metallic Compounds 1, P171, DOI 10.1016/S0168-1273(79)03007-5
[5]   A new azo rare earth coordination compound for second-order non-linear optical Langmuir-Blodgett films [J].
Gao, LH ;
Wang, KZ ;
Huang, CH ;
Zhou, YF ;
Li, TK ;
Xu, JM ;
Zhao, XS ;
Xia, XH .
THIN SOLID FILMS, 1996, 286 (1-2) :237-240
[6]  
Gorller-Walrand C, 1998, HANDB PHYSI, V25, P101, DOI 10.1016/S0168-1273(98)25006-9
[7]   Atomic force microscopy and non-linear optical studies of stilbazolium dyes in Langmuir-Blodgett layers [J].
Grummt, UW ;
Feller, KH ;
Lehmann, F ;
Colditz, R ;
Gadonas, R ;
Pugzlys, A .
THIN SOLID FILMS, 1996, 284 :904-907
[8]   OPTICAL ABSORPTION INTENSITIES OF RARE-EARTH IONS [J].
JUDD, BR .
PHYSICAL REVIEW, 1962, 127 (03) :750-&
[9]  
Li H, 1996, PROG NAT SCI, V6, P96
[10]   2ND-HARMONIC GENERATION IN LANGMUIR-BLODGETT MONOLAYERS OF STILBAZIUM SALT AND PHENYLHYDRAZONE DYES [J].
LUPO, D ;
PRASS, W ;
SCHEUNEMANN, U ;
LASCHEWSKY, A ;
RINGSDORF, H ;
LEDOUX, I .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1988, 5 (02) :300-308