(Phenylboratabenzene)zirconium complexes: Tuning the reactivity of an olefin polymerization catalyst

被引：118

作者：

Bazan, GC ^{[1
]}

Rodriguez, G ^{[1
]}

Ashe, AJ ^{[1
]}

AlAhmad, S ^{[1
]}

Kampf, JW ^{[1
]}

机构：

[1] UNIV MICHIGAN,DEPT CHEM,ANN ARBOR,MI 48109

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 12期

关键词：

D O I：

10.1021/om970103z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 2 equiv of lithium 1-phenylboratabenzene with ZrCl4 in ether affords bis(1-phenylboratabenzene)zirconium dichloride (2), while [4-tert-C4H9C5H4BPh](2)ZrCl2 (3), obtained in, a similar manner, was subjected to a single-crystal X-ray diffraction study. The reaction of a solution of 2 and methylaluminoxane (MAO) with C2H4 (1 atm, 25 degrees C) affords ethylene oligomers (dimers of 1-alkenes as the major product, together with minor amounts of 1- and 2-alkenes).

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页码：2492 / 2494

页数：3

相关论文

共 17 条

[1]

[Anonymous], ZIEGLER CATALYSTS

[2] BIS(1-SUBSTITUTED-BORABENZENE)IRON COMPLEXES [J].

ASHE, AJ ;

MEYERS, E ;

SHU, P ;

VONLEHMANN, T ;

BASTIDE, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (23) :6865-6866

[3] 1-PHENYLBORABENZENE ANION [J].

ASHE, AJ ;

SHU, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (07) :1804-&

[4] STABILIZATION OF STIBABENZENE AND BISMABENZENE BY 4-ALKYL SUBSTITUENTS [J].

ASHE, AJ ;

DIEPHOUSE, TR ;

ELSHEIKH, MY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (21) :5693-5699

[5] Aminoboratabenzenes. An evaluation of the exocyclic B-N interaction [J].

Ashe, AJ ;

Kampf, JW ;

Muller, C ;

Schneider, M .

ORGANOMETALLICS, 1996, 15 (01) :387-393

[6] Aminoboratabenzene derivatives of zirconium: A new class of olefin polymerization catalysts [J].

Bazan, GC ;

Rodriguez, G ;

Ashe, AJ ;

AlAhmad, S ;

Muller, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (09) :2291-2292

[7] ORGANOCOBALT COMPOUNDS IN THE SYNTHESIS OF PYRIDINES - AN EXAMPLE OF STRUCTURE-EFFECTIVITY RELATIONSHIPS IN HOMOGENEOUS CATALYSIS [J].

BONNEMANN, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (04) :248-262

[8] STEREOSPECIFIC OLEFIN POLYMERIZATION WITH CHIRAL METALLOCENE CATALYSTS [J].

BRINTZINGER, HH ;

FISCHER, D ;

MULHAUPT, R ;

RIEGER, B ;

WAYMOUTH, RM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (11) :1143-1170

[9] EFFECTS OF REGIOCHEMICAL AND STEREOCHEMICAL ERRORS ON THE COURSE OF ISOTACTIC PROPENE POLYINSERTION PROMOTED BY HOMOGENEOUS ZIEGLER-NATTA CATALYSTS [J].

BUSICO, V ;

CIPULLO, R ;

CHADWICK, JC ;

MODDER, JF ;

SUDMEIJER, O .

MACROMOLECULES, 1994, 27 (26) :7538-7543

[10] NOVEL AROMATIC BORON HETEROCYCLE AS LIGAND IN A TRANSITION METAL PI-COMPLEX [J].

HERBERIC.GE ;

GREISS, G ;

HEIL, HF .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1970, 9 (10) :805-&