Theoretical evaluation of cooperative luminescence rate in Yb3+:CsCdBr3 and comparison with experiment

被引：27

作者：

Goldner, P ^{[1
]}

Pelle, F ^{[1
]}

Auzel, F ^{[1
]}

机构：

[1] CNRS UPR 211,LAB PHYSICOCHIM MAT,F-92190 MEUDON,FRANCE

来源：

JOURNAL OF LUMINESCENCE | 1997年 / 72-4卷

关键词：

cooperative luminescence; Yb; pairs;

D O I：

10.1016/S0022-2313(96)00238-4

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Ytterbium-doped CsCdBr3 exhibits a strong cooperative luminescence under near-infrared excitation. The pair structure of this compound allows us to compare easily experimental and theoretical cooperative rate constants. Electrostatic, magnetic and exchange interactions as well as two types of pairs are considered. Computed values result in a cooperative rate constant of 2.2 x 10(-2) s(-1) in reasonable agreement with the experimental value. 0.13 s(-1).

引用

页码：901 / 903

页数：3

共 6 条

[1] AUZEL F, 1994, OPT MATER, V4, P35, DOI 10.1016/0925-3467(94)90053-1
[2] GOLDNER P, IN PRESS J LUMIN
[3] ENERGY-TRANSFER AND COOPERATIVE OPTICAL TRANSITIONS IN RARE-EARTH DOPED INORGANIC MATERIALS .2. COMPARISON WITH EXPERIMENTS
KUSHIDA, T
[J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1973, 34 (05) : 1327 - 1333
[4] ENERGY-TRANSFER AND COOPERATIVE OPTICAL TRANSITIONS IN RARE-EARTH DOPED INORGANIC MATERIALS .1. TRANSITION PROBABILITY CALCULATION
KUSHIDA, T
[J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1973, 34 (05) : 1318 - 1326
[5] ENERGY-TRANSFER AND COOPERATIVE OPTICAL TRANSITIONS IN RARE-EARTH DOPED INORGANIC MATERIALS .3. DOMINANT TRANSFER MECHANISM
KUSHIDA, T
[J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1973, 34 (05) : 1334 - 1337
[6] Covalent mechanism of cooperative optical transitions in lanthanide exchange-coupled pairs. Intensity calculations for double transitions in a M(2)L(11) f(1)-f(1) dimer
Mironov, VS
Kaminskii, AA
[J]. PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1996, 194 (01): : 307 - 318

← 1 →