Sinapinic acid as Al-2.5Mg alloy corrosion inhibitor in sodium chloride solution

被引:15
作者
Vrsalovic, L. [1 ]
Kliskic, M. [1 ]
Radosevic, J. [1 ]
Gudic, S. [1 ]
机构
[1] Fac Chem Technol, Dept Electrochem & Mat Protect, Split 21000, Croatia
关键词
Al-2.5Mg alloy; corrosion inhibition; phenolic acid; rotating disc electrode; sinapinic acid;
D O I
10.1007/s10800-006-9260-6
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Sinapinic acid was studied for possible use as an Al-2.5Mg alloy corrosion inhibitor in a 0.5 mol dm(-3) NaCl solution. Measurements were performed on a rotating disc electrode in a quiescent solution and at different electrode rotation rates and electrolyte temperatures. Electrochemical parameters for the Al-2.5Mg alloy were determined using polarization techniques and electrochemical impedance spectroscopy (EIS). The investigated compound acts as a cathodic-type inhibitor and the inhibition is ascribed to the adsorption of the inhibitor onto the electrode surface. The electrode coverage follows the Freundlich adsorption isotherm.
引用
收藏
页码:325 / 330
页数:6
相关论文
共 32 条
[1]   Corrosion inhibition study of pure Al and some of its alloys in 1.0 M HCl solution by impedance technique [J].
Abd El Rehim, SS ;
Hassan, HH ;
Amin, MA .
CORROSION SCIENCE, 2004, 46 (01) :5-25
[2]   Inhibition of corrosion of Al 6061, aluminum, and an aluminum-copper alloy in chloride-free aqueous media: Part 2 - Behavior in basic solutions [J].
Al-Kharafi, FM ;
Badawy, WA .
CORROSION, 1998, 54 (05) :377-385
[3]   Inhibitive action of Vernonia amygdalina on the corrosion of aluminium alloys in acidic media [J].
Avwiri, GO ;
Igho, FO .
MATERIALS LETTERS, 2003, 57 (22-23) :3705-3711
[4]   Electrochemical behaviour and corrosion inhibition of Al, Al-6061 and Al-Cu in neutral aqueous solutions [J].
Badawy, WA ;
Al-Kharafi, FM ;
El-Azab, AS .
CORROSION SCIENCE, 1999, 41 (04) :709-727
[5]   Antimicrobial intermediates of the general phenylpropanoid and lignin specific pathways [J].
Barber, MS ;
McConnell, VS ;
DeCaux, BS .
PHYTOCHEMISTRY, 2000, 54 (01) :53-56
[6]   The inhibition effect of amino acids and hydroxy carboxylic acids on pitting corrosion of aluminum alloy 7075 [J].
Bereket, G ;
Yurt, A .
CORROSION SCIENCE, 2001, 43 (06) :1179-1195
[7]   AN EIS STUDY OF ALUMINUM BARRIER-TYPE OXIDE-FILMS FORMED IN DIFFERENT MEDIA [J].
BESSONE, JB ;
SALINAS, DR ;
MAYER, CE ;
EBERT, M ;
LORENZ, WJ .
ELECTROCHIMICA ACTA, 1992, 37 (12) :2283-2290
[8]   THE APPLICATION OF ELECTROCHEMICAL IMPEDANCE TECHNIQUES TO ALUMINUM CORROSION IN ACIDIC CHLORIDE SOLUTION [J].
BRETT, CMA .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1990, 20 (06) :1000-1003
[9]   THE ELECTROCHEMICAL-BEHAVIOR AND CORROSION OF ALUMINUM IN CHLORIDE MEDIA - THE EFFECT OF INHIBITOR ANIONS [J].
BRETT, CMA ;
GOMES, IAR ;
MARTINS, JPS .
CORROSION SCIENCE, 1994, 36 (06) :915-&
[10]   ON THE ELECTROCHEMICAL-BEHAVIOR OF ALUMINUM IN ACIDIC CHLORIDE SOLUTION [J].
BRETT, CMA .
CORROSION SCIENCE, 1992, 33 (02) :203-210