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Sinapinic acid as Al-2.5Mg alloy corrosion inhibitor in sodium chloride solution
被引:15
作者:
Vrsalovic, L.
[1
]
Kliskic, M.
[1
]
Radosevic, J.
[1
]
Gudic, S.
[1
]
机构:
[1] Fac Chem Technol, Dept Electrochem & Mat Protect, Split 21000, Croatia
关键词:
Al-2.5Mg alloy;
corrosion inhibition;
phenolic acid;
rotating disc electrode;
sinapinic acid;
D O I:
10.1007/s10800-006-9260-6
中图分类号:
O646 [电化学、电解、磁化学];
学科分类号:
081704 ;
摘要:
Sinapinic acid was studied for possible use as an Al-2.5Mg alloy corrosion inhibitor in a 0.5 mol dm(-3) NaCl solution. Measurements were performed on a rotating disc electrode in a quiescent solution and at different electrode rotation rates and electrolyte temperatures. Electrochemical parameters for the Al-2.5Mg alloy were determined using polarization techniques and electrochemical impedance spectroscopy (EIS). The investigated compound acts as a cathodic-type inhibitor and the inhibition is ascribed to the adsorption of the inhibitor onto the electrode surface. The electrode coverage follows the Freundlich adsorption isotherm.
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页码:325 / 330
页数:6
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