A Study on Rain Acidification Processes in Ten Cities of China

A physico-chemical sub-cloud rain acidification model is used to simulate the acidification processes of rainwater in ten cities of China, based on the observation data of the chemical components of cloud- and rainwater and the concentrations of gaseous and aerosol species. The results show that there are in-cloud process and below-cloud process in the formation of acid rain, but the relative importance of these two processes is different in various cities. The acidification of rainwater under cloud is very important in Guiyang, Shanghai, Jilin, Beijing, Changsha and Chongqing, and the in-cloud and below-cloud process contribute equally to the acidification in Guilin, however, the acidification of rainwater in cloud is more important in Nanchang and Guangzhou. Overall, the aerosol has an alkalization effect on the rain, about 11%–25% of H+ concentration in the rainwater is neutralized over Southern China and 60%–70% is neutralied over Northern China by aerosol species. The effect of atmospheric SO2 on acidification of rainwater is nonlinear and is different in various regions. The effects of the variation of atmospheric NH3, H2O2 and aerosol species on pH of rainwater are also discussed in detail.