Influence of soil parameters on the effect of 3,4-dimethylpyrazole-phosphate as a nitrification inhibitor

被引:136
作者
Barth G. [1 ]
Von Tucher S. [1 ]
Schmidhalter U. [1 ]
机构
[1] Technical University Munich
关键词
3,4-Dimethylpyrazole-phosphate; Adsorption; Nitrification inhibitor; Short-term incubation; Soil texture;
D O I
10.1007/s003740100382
中图分类号
学科分类号
摘要
Nitrification inhibitors specifically retard the oxidation of NH4+ to NO2- during the nitrification process in soil. In this study, the influence of soil properties on the nitrification-inhibiting effect of 3,4-dimethylpyrazole-phosphate (DMPP), a newly developed nitrification inhibitor, has been investigated. Based on short-term incubation experiments, where the degradation of DMPP could be largely disregarded, the oxidation of the applied NH4+ was more inhibited in sandy soils compared with loamy soils. The influence of soil parameters on the relative NO2- formation could be described by a multiple regression model including the sand fraction, soil H+ concentration and soil catalase activity (R2=0.62). Adsorption studies showed that the binding behaviour of DMPP was influenced markedly by soil textural properties, viz. the clay fraction (r2=0.61). The adsorption of DMPP was found to be an important factor for the inhibitory effect on NH4+ oxidation in a short-term incubation (r2-0.57). It is concluded that the evaluated soil properties can be used to predict the short-term inhibitory effect of DMPP in different soils. The significance of these results for long-term experiments under laboratory and field conditions needs further investigation.
引用
收藏
页码:98 / 102
页数:4
相关论文
共 23 条
[1]  
Abdel-Sabour M.F., Massoud M.A., Baveye P., The effect of water movement on transport of dicyandiamide, ammonium and urea in unsaturated soils, Z Pflanzenernaehr Bodenkd, 153, pp. 245-247, (1990)
[2]  
Amberger A., Vilsmeier K., Untersuchungen zur Auswaschung von Dicyandiamid und dessen Abbau in überstauten Böden, Z Wasser Abwasser Forsch, 21, pp. 140-144, (1988)
[3]  
Beck T., Die Messung der Katalaseaktivität von Böden, Z Pflanzenemaehr Bodenkd, 130, pp. 68-81, (1971)
[4]  
Belser L.W., Mays E.L., Specific inhibition of nitrite oxidation by chlorate and its use in assessing nitrification in soils and sediments, Appl Environ Microbiol, 39, pp. 505-510, (1980)
[5]  
Berg P., Rosswall T., Ammonium oxidizer numbers, potential and actual oxidation rates in two swedish arable soils, Biol Fertil Soils, 1, pp. 131-140, (1985)
[6]  
Bobe A., Coste C.M., Cooper J.-F., Factors influencing the adsorption of fipronil on soils, J Agric Food Chem, 45, pp. 4861-4865, (1997)
[7]  
Calamai L., Ristori G.G., Fusi P., Interactions of catalase with inorganic and organic surfaces, Agrochimica, 25, pp. 280-284, (1991)
[8]  
Corre W.J., Zwart K.B., Effects of DCD addition to slurry on nitrate leaching in sandy soils, Neth J Agric Sci, 43, pp. 195-204, (1995)
[9]  
Fettweis U., Mittelstaedt W., Schimansky C., Fuhr F., Lysimeter studies on the translocation of the <sup>14</sup>C-labelled nitrification inhibitor DMPP in a gleyic cambisol, Biol Fertil Soils, (2001)
[10]  
Fusi P., Ristori G.G., Calamai L., Stotzky G., Adsorption and binding of protein on "clean" (homoionic) and "dirty" (coated with Fe oxyhydroxides) montmorillonite, illite and kaolinite, Soil Biol Biochem, 21, pp. 911-920, (1989)