Mobile laser spectrometer with novel resonant multipass photoacoustic cell for trace-gas sensing

被引:117
作者
M. Nägele
M.W. Sigrist
机构
[1] Swiss Federal Institute of Technology (ETH),
[2] Institute of Quantum Electronics,undefined
[3] Laboratory for Laser Spectroscopy and Environmental Sensing,undefined
[4] 8093 Zürich,undefined
[5] Switzerland (Fax: +41-1/633-1077,undefined
[6] E-mail: sigrist@iqe.phys.ethz.ch),undefined
关键词
PACS: 82.Ch;
D O I
10.1007/PL00021151
中图分类号
学科分类号
摘要
The development and application of a mobile laser-photoacoustic spectrometer for in situ multicomponent monitoring of trace gases in different environments is reported. Sub-ppbV (<10-9 per volume)-concentrations can be measured with a novel resonant multipass photoacoustic cell. The cell is designed for flow mode operation in order to reduce adsorption effects. For ethene (C2H4) buffered in synthetic air a minimum detection limit of 70 ppt V (70×10-12 per volume) is achieved corresponding to a minimum measurable absorption coefficient αmin=2×10-9 cm-1 for a signal-to-noise ratio of 3. The multicomponent capability of the system is demonstrated with continuous sequential measurements of ethene, methanol, ethanol, CO2, and H2O of air from a fruit storage chamber.
引用
收藏
页码:895 / 901
页数:6
相关论文
empty
未找到相关数据