Stereocontrolled synthesis of the alkaloid (-)-actinidine

被引：1

作者：

Stepanov A.V. ^{[1
]}

Lozanova A.V. ^{[1
]}

Veselovsky V.V. ^{[1
]}

机构：

[1] N. D. Zelinsky Inst. of Organ. Chem., Russian Academy of Sciences, 117913 Moscow

来源：

Russian Chemical Bulletin | 1998年 / 47卷 / 11期

关键词：

(-)-actinidine; (-)-citronellal; (-)-citronellol; Alkaloid; Intramolecular [3+2] dipolar cycloaddition; Iridoid; N-alkyl-N-phenylthiohydroxyl-amine; Silyl nitronate; Vinyl sulfide;

D O I：

10.1007/BF02494297

中图分类号：

学科分类号：

摘要：

The alkaloid (-)-actinidine of the iridane series was synthesized using intramolecular [3+2] dipolar cycloaddition of silyl nitronates, generated from (3R/S,6S)-2,6-dimethyl-3-nitro-8-phenylthioocta-1,7E-and -1,7Z-dienes. The key nitro compounds were obtained from (-)-(S)-citronellol.

引用

页码：2286 / 2291

页数：5

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