Molecular hydrogen-originated protonic acid site as active site on solid acid catalyst

被引：21

作者：

Hattori H. ^{[1
]}

Shishido T. ^{[1
]}

机构：

[1] Center for Advanced Research of Energy Technology, Hokkaido University, Kita-ku, Kita-13, Nishi-8

来源：

Catalysis Surveys from Asia | 1997年 / 1卷 / 2期

关键词：

Co.Mo/SiO2-Al2O3; H-ZSM5; Hydrogen; Protonic acid site; Pt/SO42--ZrO2; Solid acid; Spillover;

D O I：

10.1023/A:1019081031021

中图分类号：

学科分类号：

摘要：

The protonic acid sites are formed from hydrogen molecules on Pt/SO42 -ZrO2, and the resulting protonic acid sites act as active sites for acid-catalyzed reactions. Promotion of molecular hydrogen on the activities is observed not only for the Pt/SO42--ZrO2, but also for the other catalysts such as a physical mixture of Pt/SiO2 and H-ZSM5, and Co.Mo/SiO2-Al2O3. A molecular hydrogen-originated protonic acid site is proposed as a widely applicable concept for an active site on solid acid catalysts. © Baltzer Science Publishers BV.

引用

页码：205 / 213

页数：8

共 27 条

[1] Dent, A.L., Kokes, R.J., (1969) J. Phys. Chem., 72, p. 2436
[2] Kokes, R.J., Dent, A.L., (1971) Adv. Catal. Relat. Subj., 22, p. 1
[3] Coluccia, S., Tench, A.J., (1980) Proceedings of the 7th International Congress on Catalysis, p. 1154. , Kodansha
[4] Nakano, Y., Iizuka, T., Hattori, H., Tanabe, K., (1978) J. Catal., 57, p. 1
[5] Imizu, Y., Sata, K., Hattori, H., (1982) J. Catal., 57, p. 65
[6] Imizu, Y., Hattori, H., Tanabe, K., (1979) J. Catal., 57, p. 35
[7] Hosoi, T., Shimadzu, T., Ito, S., Baba, S., Takaoka, H., Imai, T., Yokoyama, N., (1988) Prep. Symp. Div. Petro. Chem. Am. Chem. Soc., p. 562. , Los Angeles Meeting
[8] Hattori, H., Ebitani, K., Tanaka, T., Tanabe, K., (1991) Catalytic Science and Technology, 1, p. 117. , Kodansha-VCH
[9] Hattori, H., (1993) Proceedings of the 3rd International Conference on Spillover, p. 69. , Kyoto, Elsevier
[10] Kikuchi, E., Matsuda, T., (1993) Proceedings of the 3rd International Conference on Spillover, p. 53. , Kyoto, Elsevier

← 1 2 3 →