Analysis and occurrence of polybrominated diphenyl ethers in Washington state freshwater fish

被引:91
作者
Johnson A. [1 ]
Olson N. [2 ]
机构
[1] Washington State Department of Ecology, Environmental Assessment Program, Olympia, WA 98504-7710
[2] Washington State Department of Ecology, Manchester Environmental Laboratory, Port Orchard, WA 98366
关键词
Rainbow Trout; Penta; Bromine; Atomic Emission; Fish Tissue;
D O I
10.1007/s002440010257
中图分类号
学科分类号
摘要
A method is described for analyzing polybrominated diphenyl ethers (PBDEs) in fish tissue using gas chromatography with atomic emission detection (GC/AED) and quantitation by compound independent calibration (CIC). The method has the advantage of an element-selective response, including selectivity between bromine and chlorine. An analysis of fish tissue samples from selected locations in Washington State showed total PBDE concentrations ranged from 1.4 μg/kg (wet weight) in rainbow trout from a remote spring-fed stream to 1,250 μg/kg in mountain whitefish from the urbanized Spokane River. Tetra and penta isomers were the major compounds present. There appear to be substantial between-species differences in the ability of fish to metabolize PBDEs.
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页码:339 / 344
页数:5
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