Stability of complex molybdenum(III) ions in molten alkali metal chlorides

被引：8

作者：

Kamalov, R.V. ^{[1
]}

Volkovich, V.A. ^{[1
]}

Polovov, I.B. ^{[1
]}

Vasin, B.D. ^{[1
]}

机构：

[1] Ural Federal University, Yekaterinburg 620002

来源：

Russian Metallurgy (Metally) | 2012年 / 2012卷 / 02期

关键词：

Cesium compounds - Mixtures - Molybdenum compounds - Potassium compounds - Sodium chloride - Lithium compounds;

D O I：

10.1134/S0036029512020097

中图分类号：

TF826 [碱金属]; TG146.2+6 [碱金属];

学科分类号：

080603 [有色金属冶金];

摘要：

High-temperature absorption spectroscopy is used to study the effect of temperature in the range 550-750°C and the cation composition of a solvent salt on the spectroscopic characteristics and stability of MoCl 6 3- complex ions in melts based on alkali metal chlorides (LiCl; CsCl; LiCl-KCl, NaCl-CsCl, KCl-CsCl, and NaCl-KCl-CsCl eutectic mixtures; and equimolar NaCl-KCl mixture). © 2012 Pleiades Publishing, Ltd.

引用

页码：114 / 118

页数：4

共 19 条

[1]

Senderoff S., Brenner A., The Electrolytic Preparation of Molybdenum from Fused Salts: I. Electrolytic Studies, J. Electrochem. Soc., 101, pp. 16-27, (1954)

[2]

Senderoff S., Brenner A., The Electrolytic Preparation of Molybdenum from Fused Salts: III. Studies of Electrode Potentials, J. Electrochem. Soc., 101, pp. 31-38, (1954)

[3]

Volkovich V.A., Griffiths T.R., Thied R.C., Et al., Behavior of Molybdenum in Pyrochemical Reprocessing: A Spectroscopic Study of the Chlorination of Molybdenum and Its Oxides in Molten Chlorides, J. Nucl. Mater., 323, pp. 93-100, (2003)

[4]

Gabriel J.C., Vincent D., Bouteillon J., Et al., Molybdenum Chemistry in Molten LiCl-KCl Eutectic and Electrochemical and Absorption Spectroscopy Study of the Concentration Dependent Stability of Solutions of K <sub>3</sub>MoCl <sub>6</sub> , Electrochim. Acta, 44, pp. 4619-4629, (1999)

[5]

Aleksandrov E.P., Vasin B.D., Kazakov A.S., Et al., Absorption Spectra of Trivalent Molybdenum in Molten Chlorides, Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 6, pp. 134-136, (1978)

[6]

Aleksandrov E.P., Alekseev A.B., Vasin B.D., Et al., Absorption Spectra of Molybdenum-Containing Chloride Melts, Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 1, pp. 66-70, (1981)

[7]

Arkhipov P.A., Baraboshkin A.N., Valeev Z.I., Et al., Electrodeposition of Molybdenum from Low-Temperature Chloride Baths, Electrokhimiya, 26, pp. 1555-1560, (1990)

[8]

Senderoff S., Mellors G.W., Electrodeposition of Coherent Deposits of Refractory Metals: V. Mechanism for the Deposition of Molybdenum from a Chloride Melts, J. Electrochem. Soc., 114, pp. 556-560, (1967)

[9]

Kipouros G.J., Sadoway D., The Electrodeposition of Improved Molybdenum Coatings from Molten Salts by the Use of Electrolyte Additives, J. Appl. Electrochem., 18, pp. 823-830, (1988)

[10]

Volkovich V.A., May I., Charnock J.M., Et al., Reactions and Speciation of Technetium and Rhenium in Chloride Melts: a Spectroscopy Study, Phys. Chem. Chem. Phys., 4, pp. 5753-5760

← 1 2 →