Capillary electrochromatographic separation of amino acid enantiomers with molecularly imprinted polymers as chiral recognition agents

被引:1
作者
J.-M. Lin
Tatsuro Nakagama
Xing-Zheng Wu
Katsumi Uchiyama
Toshiyuki Hobo
机构
[1] Department of Industrial Chemistry,
[2] Faculty of Engineering,undefined
[3] Tokyo Metropolitan University,undefined
[4] Minami-Ohsawa 1-1,undefined
[5] Hachioji-Shi,undefined
[6] 192-03 Tokyo,undefined
[7] Japan,undefined
来源
Fresenius' Journal of Analytical Chemistry | 1997年 / 357卷
关键词
Polymer; Preliminary Report; Methacrylic Acid; Inside Surface; Functional Monomer;
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摘要
The use of molecularly imprinted polymers polymerized in a capillary for the separation of amino acid enantiomers by electrochromatography is described. The substrate-selective polymers were prepared by using l-phenylalanine anilide as print molecule and methacrylic acid as the functional monomer. The treatment of the inside surface of the capillary, the composition of the polymer and the electrochromatographic running conditions were investigated. This preliminary report demonstrated a novel and simple method for capillary electrochromatographic separations of amino acid enantiomers using molecularly imprinted polymers.
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页码:130 / 132
页数:2
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